Scott, not sure how your car is wired but here is what I did with mine.
I bought a 4 pole cutoff switch.
The main terminal is for the positive battery cable.
Most cars if you cut off the 12+ battery cable it will not kill the engine.
The alternator will allow the car to continue to run. You can test this by disconnecting the positive battery cable while the car is running. My daily driver E30 beater I swapped batteries with my tow rig while it was running when the rig would not spin over.
The other is for the 12+ from the alternator to the battery. Careful here you may need a diode to protect the alternator. BMW has this built in from the factory. If you look you can find diagrams. Maybe on a VW forum? Someone else has gone through this.
If done the way above not only will the switch kill the engine but will kill power to the entire car which is the goal safety wise. It is not about "restarting" it is about power killing to everything in event of throttle stick, fire, etc.
Also try to mount it where it is easy for the workers/safety people to get to. They need easy access more then you do. Needs to be accessible if your car is upside down or on its side also.
Mine is not perfect but is on the top of the dash just inside the passenger door window opening and is clearly marked and very visible. I hope to run a second switch in the same place but on the driver's side. That way no matter how the car is laying or which side is responded too the switch is there for them.
I have seen an expensive but very trick setup using 1 main cut off switch operated by a solenoid. You mount this anyplace and then run as many small 12v toggle switches as you like where ever you like. Internet search will find them for you.
I don't know VW's but with my car BMW had already put the battery in the trunk so both positive cables battery-alternator were already there to tap in to. And since BMW puts "jumper terminals" in the engine compartment it was really easy.
So you might want to see if your car has something similar. They are both German
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